Product ID:48225 EPA EDB/DBCP MIX/1X1ML/MEOH/2000UG/ML EACH
MSDS Date:03/18/1994
FSC:6810
NIIN:00F037974
MSDS Number: BWKHG

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

DIBROMOETHANE, ETHYLENE DIBROMIDE, 1,2-DIBROMOETHANE

CAS: 106-93-4

RTECS: KH9275000

Fraction By Weight: 0.2%

ACGIH TLV: A2 CARCINOGEN

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1,2-DIBROMO-3-CHLOROPROPANE (ANIMAL CARCINOGEN BY

CAS: 96-12-8

RTECS: TX8750000

Fraction By Weight: 0.2%

ACGIH TLV: NONE

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS *94-4*

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99-100%

OSHA PEL 260 MG/CUM

ACGIH TLV: 262 MG/CUM (SKIN)

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:ORAL LD50(RAT): 5628 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. MAY CAUSE HEADACHE, NAUSEA, GASTROINTESTINAL
DISTURBANCES, BLINDNESS.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:HEADACHE, NAUSEA, GASTROINTESTINAL
DISTURBANCES.

First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: FLUSH W/PLENTY OF
WATER. INHALATION: IMMEDIATELY MOVE TO FRESH AIR. IF BREATHING
STOPS, GIVE CPR. INGESTION: NEVER GIVE ANYTHING BY MOUTH IF
UNCONSCIOUS. NEVER T RY TO MAKE AN UNCONSCIOUS PERSON VOMIT.GIVE 2
TABLESPOONS OF BAKING SODA IN A GLASS OF WATER, PRESS FINGERS TO
BACK OF TONGUE TO INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL
CASES.

Flash Point:50F
Lower Limits:6
Upper Limits:36.5
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS WHEN
FIGHTING A CHEMICAL FIRE.
Unusual Fire/Explosion Hazard:TOXIC VAPORS ARE FORMED WHEN THIS
MATERIAL IS HEATED TO DECOMPOSITION.

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS & IGNITION SOURCES. USE ONLY IN A WELL
VENTILATED AREA.
Other Precautions:AVOID EYE/SKIN CONTACT. AVOID BREATHING VAPORS.

Respiratory Protection:WEAR FACE MASK W/ORGANIC VAPOR CANISTER.
Ventilation:REQUIRED
Protective Gloves:RUBBER
Eye Protection:PROTECTIVE GLASSES.
Supplemental Safety and Health

Boiling Pt:B.P. Text:98.8F
Melt/Freeze Pt:M.P/F.P Text:-144.4F
Vapor Pres:100
Vapor Density:1.1
Spec Gravity:0.79
Evaporation Rate & Reference:(ETHER=1): >1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC ACIDS
Stability Condition to Avoid:IGNITION SOURCES.
Hazardous Decomposition Products:HYDROGEN BROMIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.